The combined effect of reduced fossil fuel consumption and increasing biomass combustion on Athens' air quality, as inferred from long term CO measurements.

To evaluate the role of biomass burning emissions, and in particular of residential wood heating, as a result of the economic recession in Greece, carbon monoxide (CO) atmospheric concentrations from five (5) stations of the National Air Pollution Monitoring Network in Athens, spanning the period 2000-2015, in conjunction with black carbon (BC) concentrations from the NOA (National Observatory of Athens) station at Thissio were analysed. The contribution of the different sources to the diurnal cycle of these two pollutants is clear, resulting to a morning peak, mainly due to traffic, and a late evening peak attributed both to fossil fuel (traffic plus central heating) and biomass combustion. Calculated morning and evening integrals of CO peaks, for the investigated period, show consistent seasonal modulations, characterised by low summer and high winter values. The summer and winter morning CO peak integrals demonstrate an almost constant decreasing trend of CO concentrations over time (by almost 50% since 2000), attributed to the renewal of passenger car fleet and to reduced anthropogenic activities during the last years. On the other hand, an increase of 23%-78% (depending on the monitoring site) in the winter evening integrals since 2012, provides evidence of the significant contribution of biomass combustion, which has prevailed over fossil fuel for domestic heating. CO emitted by wood burning was found to contribute almost 50% to the total CO emissions during night time (16:00-5:00), suggesting that emissions from biomass combustion have gained an increasing role in atmospheric pollution levels in Athens.